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Alpha-Terpinene

Citrus-like, oxidizes — regulated under EU Regulation 2023/1545 (expansion of declarable fragrance allergens from 26 to 81+).

Prepared by Allergen81 Compliance Team · Last reviewed September 2026. Provided for information only — always verify against the official regulation and your responsible person's assessment.

Sources & references

  • Commission Regulation (EU) 2023/1545 — full text on EUR-Lex
  • CosIng — the European Commission's cosmetic ingredient database
  • PubChem (NIH) — substance record for CAS 99-86-5
Pre-hapten: oxidizes on air exposure to Terpinene hydroperoxides — stronger sensitizers. Store cool, dark, and use antioxidants where appropriate.

CAS Number

99-86-5

EC Number

202-785-3

INCI Name

ALPHA-TERPINENE

Status

Declarable

Declaration thresholds (EU 2023/1545)

Leave-on products

0.100%

= 10 mg/kg (10 ppm)

Rinse-off products

1.00%

= 100 mg/kg (100 ppm)

Alpha-Terpinene must be separately declared in the ingredient list (INCI) when its concentration in the finished product exceeds these values. Below the threshold, no separate mention is required.

Essential oils containing Alpha-Terpinene

Typical concentration ranges (of the oil itself, not the finished product):

Lemon Oil0.1–0.5%Tea Tree Oil5–13%

Example: at 1.5% lavender oil in a leave-on cream with linalool at up to 45%, the product contains up to ~0.68% linalool — far above the 0.001% threshold, so it must be declared.

Check your formula against Alpha-Terpinene automatically

Upload your supplier PDFs and Allergen81 extracts every allergen, runs the threshold math (including pre-hapten grouping), and generates your INCI-compliant label.

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Alpha-Terpinene — FAQ

When does Alpha-Terpinene need to be declared on a cosmetic label?

Under EU Regulation 2023/1545, Alpha-Terpinene must be listed separately in the ingredient declaration (INCI) when its concentration in the finished product exceeds 0.100% in leave-on products or 1.00% in rinse-off products.

Which essential oils contain Alpha-Terpinene?

Alpha-Terpinene naturally occurs in: Lemon Oil, Tea Tree Oil. Typical concentration ranges in these oils vary — always confirm with a supplier IFRA certificate or GC/MS report.

Does Alpha-Terpinene oxidize?

Yes. Alpha-Terpinene is a pre-hapten: on air exposure it oxidizes to Terpinene hydroperoxides, which are stronger sensitizers. Fresh product and antioxidant-stabilized formulations reduce this risk.

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